2,2-Anhydro-1-beta-D-arabinofuranosylcytosine hydrochloride

Asia Bio-Pharmaceutical Research Institute

2,2-Anhydro-1-beta-D-arabinofuranosylcytosine hydrochloride

Product name:2,2'-Anhydro-1-beta-D-arabinofuranosylcytosine hydrochloride
CAS:10212-25-6
Molecular Formula:C9H12ClN3O4
Formula Weight:261.66
Specification:5g
Description:2,2' -anhydro-1-bet-d-arabinofuranosylcytosine suitable for white needle-like crystal or crystalline powder; Odourless; It is soluble in water, slightly soluble in methanol and ethanol, almost insoluble in ether, benzene and chloroform.

Calcium gluconate (m) : water (V) : hydrogen peroxide (30%, V) : ferric gluconate solution (10%, V) : 95% ethanol (V)= 1:8.1:0.88:0.22:0.3. Pour calcium gluconate into 90℃ water and bring to a boil. After stirring for 10min, the temperature was lowered to 70℃, and ferric gluconate was added. After stirring for 10min, the temperature drops to 65℃. Hydrogen peroxide is added every 20min and finished within 6h. Meanwhile, the temperature is maintained at 60-65℃. After the reaction was completed, the filtrate was cooled and filtered. The filtrate was passed through strong acid styrene cation exchange resin 007×7(732) and strong basic quaternary ammonium I anion exchange resin 201×7(717). The collected liquid was reduced to concentration under 60℃, 95% ethanol was added, and then overnight, filtered and dried to obtain 2,2' -anhydro-1-bet-d-arabinofuranosylcytosine.
Melting point:269-270 °C (dec.)(lit.)
Boiling point:442 °C at 760 mmHg
Flash Point:221.1 °C
Density:2.01g/cm3
Chemical property:white fine crystalline powder
Use:Used as antineoplastic.
 

 

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